搜索 - 科创网

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内容：O2在碳棒上析出，碳棒会受到强烈腐蚀，这时碳棒（石墨电极）就不能看作惰性电极了。,特别是原子氧或者初生态氧，会强烈腐蚀石墨生成CO2，加之很多石墨电极都是人造石墨（干电池中的碳棒就是），这种人造石墨内部并非完全致密的晶体结构，存在很多空隙，原子氧更容易对空隙处造成腐蚀，最终就会造成石墨电极表面腐蚀粉化,石墨能在一定程度上耐Cl2的腐蚀，因此氯碱工业阳极可以用石墨电极，但在阳极析出氧气或者生成某些强氧化性物质（例如过硫酸根离子、高氯酸根离子等）的情况下，石墨会受到强烈腐蚀，此时阳极材料不能选用石墨，工业上一般都选用,隔膜电解槽以石墨作为阳极，铁作为阴极，电解电流一般为kA级，饱和食盐水连续（非常重要！）,阳极上，即使是饱和食盐水，Cl-浓度很高，OH-浓度很低，如果只考虑理论电极电势，也应该是OH-容易放电，但O2在石墨阳极上析出的超电势可达1V左右，远高于Cl2在石墨阳极上析出的超电势（0.2V左右）

内容：最后生成高氯酸钾和氢气，加热氯酸钾可能会因为一些杂质出现危险而不建议使用，虽然电解法成本低使用方便，但是这个办法对电极有着较高的要求，之前我用铜就被严重腐蚀了，LZ可以尝试银或者铂作为电极，实在没有用石墨也行,，但是铅笔芯不行，可以去买专门的石墨电极价格也不贵，至于石墨电极的效果怎么样我也不知道了。

内容：引用 Johnny-Wei:还可能成为太阳能发电板，石墨烯发射电子，然后带上正电荷，不知道有没有这种可能发射的电子如果能被另一个电极俘获，形成回路，有可能。

约找到 1352 条结果，耗时 0.193 秒

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